Polymethylene polyphenyl polyisocyanate CAS#9016-87-9

  1. This product exhibits high chemical reactivity with active hydrogen-containing compounds, enabling efficient curing and cross-linking reactions with polyether and polyester polyols. It delivers outstanding bonding strength, superior thermal insulation performance, excellent mechanical rigidity and good dimensional stability for finished polyurethane products.
  2. With reliable weather resistance, flame retardant potential and durable structural stability, it serves as a core raw material for manufacturing rigid polyurethane foam, polyurethane adhesives, sealants, industrial coatings and composite elastomers. It is widely applied in construction thermal insulation, cold chain refrigeration, automotive interior parts, electrical equipment insulation, waterproof plugging and new synthetic material industries.
  3. Strictly factory-produced with stable batch quality, our products adopt standardized production and quality inspection systems. We provide premium-grade materials and professional after-sales technical support to ensure stable and long-term cooperative supply for global customers.

Product Description

Polymethylene polyphenyl polyisocyanate is a brown transparent liquid with a typical pungent odor at room temperature. As a polymeric aromatic isocyanate, it features stable molecular structure, moderate viscosity and excellent cross-linking activity. Insoluble in water, it can be well dissolved and miscible with most conventional organic solvents, ensuring convenient formulation and industrial processing.

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Polymethylene polyphenyl polyisocyanate Chemical Properties

Boiling point 

392 °C5 mm Hg

density 

1.2 g/mL at 25 °C(lit.)

vapor density 

8.6 (vs air)

refractive index 

n20/D 1.634

Fp 

>230 °F

storage temp. 

Refrigerator, Under inert atmosphere

solubility 

DMSO (Sparingly), Ethyl Acetate (Slightly), Methanol (Soluble)

form 

Oil

color 

Yellow to Orange

Stability:

Stable. Incompatible with strong oxidizing agents, alcohols. May decompose in moist air, or on contact with water.

InChI

InChI=1S/C7H5NO.CH2O/c9-6-8-7-4-2-1-3-5-7;1-2/h1-5H;1H2

InChIKey

JTEOXXUIKUHXLD-UHFFFAOYSA-N

SMILES

O=C=NC1C([H])=C([H])C([H])=C([H])C=1[H].O=C([H])[H]

IARC

3 (Vol. 19, Sup 7) 1987

EPA Substance Registry System

Polymeric diphenylmethane diisocyanate (9016-87-9)

Safety Information

Hazard Codes 

Xn,T+,T,F

Risk Statements 

20-36/37/38-42-42/43-26-22-39/23/24/25-23/24/25-11-20/21/22

Safety Statements 

26-28-38-45-36/37-23-16-7-36

WGK Germany 

3

RTECS 

TR0350000

Hazardous Substances Data

9016-87-9(Hazardous Substances Data)

Product Application of Polymethylene Polyphenyl Polyisocyanate (CAS#9016-87-9)

Polymethylene polyphenyl polyisocyanate is a key raw material for synthesizing polyurethane polymers. It is extensively deployed across multiple industrial sectors:

Construction field: Fabrication of thermal insulation rigid foam and construction sealants

Automobile manufacturing: Production of shock-absorbing and sound-insulating polyurethane interior materials

Electrical industry: Insulation filling materials for electrical components and equipment

Household goods: Elastic polyurethane foam for mattresses and upholstered cushions

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